Ukraine's Prosecutor General's Office said it had launched a pre-trial investigation into possible "negligence" surrounding storage conditions at the warehouse.
At least 37 people were killed after a Russian drone strike caused a major fire and explosions at a warehouse overnight, according to local authorities.
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Tymur Tkachenko, the head of the Kyiv Oblast Military Administration, said at least 42 people, including four children, were also injured in the attack on the village of Myla, with around 400 people evacuated from the area.
"The attack caused a large-scale fire. The fire also spread to private residential buildings," Tkachenko wrote in a post on Telegram.
He added that the fire was "accompanied by explosions."
Emergency and rescue teams are continuing to work at the scene.
Ukraine's Prosecutor General's Office said it has since launched a pre-trial investigation into possible "negligence" surrounding storage conditions at the warehouse.
"In particular, the legality of the placement and storage of explosive objects and materials on the territory of the enterprise, the availability of the necessary permits and approvals, as well as the actions of officials who made the relevant decisions will be checked," it said in a statement.
Video footage circulating on social media, seemingly taken near the scene, shows a huge explosion and fireball rising into the night sky.
Ammunition storage facility
In a post on X, Ukrainian President Volodymyr Zelenskyy described the facility hit in the "first" strike as an "ammunition storage site that definitely shouldn’t have been there."
The facility was used to house drones, shells, mines, and other ammunition for the Ukrainian military, he said, while calling it a "terrible situation and terrible negligence on the part of those who stored explosives right next to people."
Russian strikes kill one in Kherson
On Saturday, two people were also killed following a Russian drone strike on Kherson in southern Ukraine. A 44-year-old also suffered a blast injury and shrapnel wounds to their chest in the attack on the city.
In the southern Odesa region, one person was killed and three others injured in another Russian attack in which eight trucks transporting food were set ablaze, officials said.
Another two people were injured in an attack on Kyiv's Sviatoshynskyi district, per local authorities.
Ukraine's air force said Russia had launched one Onyx anti-ship missile, one Iskander ballistic missile, and 267 drones at Ukraine since 6 pm on Friday.
Local air defences had shot down or "neutralised" 233 of the drones as of Saturday morning, it added.
Moscow and Kyiv have been ramping up long-range strikes in recent months, particularly targeting logistics and energy facilities.
Zelenskyy has called on his forces to further "step up" their deep strikes on Russia, setting a target of 1,000 drone launches a day.
"Right now, we average over 300 of our long-range sanctions - there must be more," he said in a video address on Friday evening.